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Reaction of thiols with the one-equivalent oxidants neptunium(VI) and cerium(IV) in aqueous acidic media

✍ Scribed by Lavallee, D. K.; Sullivan, J. C.; Deutsch, E.


Book ID
126797440
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
448 KB
Volume
12
Category
Article
ISSN
0020-1669

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## Abstract The kinetics and mechanism of cerium(IV) oxidation of hexitols, i.e. D‐sorbitol and D‐mannitol, in aqueous sulfuric acid media have been studied in the presence and absence of surfactants. Under the kinetic conditions, [S]~T~ ≫ [Ce(IV)]~T~, where [S]~T~ is the total substrate (D‐sorbito