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Metal-ion oxidative decarboxylations. 9. Reaction of benzilic acid with cerium(IV) in acidic perchlorate and sulfate media

✍ Scribed by Hanna, Samir B.; Sarac, Sezai A.

Book ID
127140515
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
730 KB
Volume
42
Category
Article
ISSN
0022-3263

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## Abstract The Ce(IV) oxidation of the five‐, six‐, and seven‐membered ring α‐hydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium