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Metal ion oxidative decarboxylations. 13. Kinetics and mechanisms of the oxidation of N-benzyliminodiacetic acid with cerium(IV) in acidic perchlorate and acidic sulfate mediums

✍ Scribed by Hanna, Samir B.; Moehlenkamp, Marilyn E.

Book ID
126898367
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
925 KB
Volume
48
Category
Article
ISSN
0022-3263

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Kinetics and mechanism of the cerium (IV
Kinetics and mechanism of the cerium (IV) oxidation of Ξ±-Hydroxycycloalkanecarboxylic acids and cyclic alcohols in acidic perchlorate media
✍ Samir B. Hanna; Jeff Taylor Fenton πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 673 KB

## Abstract The Ce(IV) oxidation of the five‐, six‐, and seven‐membered ring α‐hydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium