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Kinetics and mechanisms of the reactions of a nickel(IV) complex with iron(II), vanadium(IV), and nickel(II) cyclam ions in aqueous perchlorate media

โœ Scribed by Macartney, D. H.; McAuley, A.

Book ID
120185513
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
618 KB
Volume
22
Category
Article
ISSN
0020-1669

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Studies in nickel(IV) chemistry. Electron transfer kinetics of the reaction between tris(dimethylglyoximato)nickelate(IV) and hexacyanoferrate(II) in aqueous medium
โœ R. Sahu; G. Neogi; S. Acharya; R. K. Panda ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 534 KB

The kinetics of electron transfer from hexacyanoferrate(I1) to tris(dimethylg1yoximato)nickelate(IV), Ni(dmg)g-, to produce Fe(CN)t-and Ni(dmgH)2, follows a pseudo-first-order disappearance in the Ni(1V). The pseudo-first-order rate constants hob8 are linearly dependent on [Fe(CN);-]o in a fiftyfold