The kinetics of oxidation of ethanol by cerium(1V) in presence of ruthenium(II1) (in the order of mol dm-3) in aqueous sulfuric acid media have been followed at different temperatures (25-40Β°C). The rate of disappearance of cerium(1V) in the title reaction increases sharply with increasing [CzH50H]
Kinetics and mechanism of the ruthenium(III) chloride catalyzed oxidation of butanone-2 and pentanone-3 by cerium(IV) sulfate in aqueous sulfuric acid medium
β Scribed by Singh, M. P.; Singh, H. S.; Verma, M. K.
- Book ID
- 118136456
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 434 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0022-3654
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## Abstract The oxidation of Dβmannitol by cerium(IV) has been studied spectrophotometrically in aqueous sulfuric acid medium at 25Β°C at constant ionic strength of 1.60 mol dm^β3^. A microamount of ruthenium(III) (10^β6^ mol dm^β3^) is sufficient to enhance the slow reaction between Dβmannitol and