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The preparation of (14C) and [3H] labelled benzene oxide

✍ Scribed by Karl L. Platt; Franz Oesch

Publisher
John Wiley and Sons
Year
1977
Tongue
French
Weight
264 KB
Volume
13
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Benzene oxide ‐[U‐^14^C] was prepared from benzene ‐(U‐^14^C) by modifications of methods described for the inactive compound.

Benzene oxide‐[3.6–^3^H] was prepared by decomposition of 3.6‐bis‐trimethylsilyl‐1,4‐cyclohexadiene with tritiated water. bromination of the 1,4‐cyclohexadiene‐[3,6‐^3^H] so obtained. epoxidation and dehydrobromination.

With the latter method benzene oxide‐[3,6–^3^H] can be prepared at a much lower cost and higher specific activity than benzene oxide‐[U‐^14^C].

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