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The preparation and solvolysis of 2-chlorotricyclo[3.3.0.03,7]octane

✍ Scribed by Peter K. Freeman; Robin B. Kinnel; Timothy D. Ziebarth

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
221 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

Our interest in the hydrocarbon tricyclo[3.3.0.0Jt7 Ioctane (l) has been stimulated by its bisnor relationship to adamantane (zero carbon bridges between C-l-C-5 and C-3-C-7 rather than one carbon bridges), its symmetry (Dad) and the fact that it contains the most twisted norbornane skeleton of record. It was felt that a study of the chemistry associated with the

πŸ“œ SIMILAR VOLUMES

A synthesis of tricyclo[3.3.0.03,7]Octan
A synthesis of tricyclo[3.3.0.03,7]Octane (bisnoradamantane); solvolysis of its mono and dicarbinols
✍ B.Richard Vogt; Stuart R. Suter; John R.E. Hoover πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 220 KB

We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV)