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A synthesis of tricyclo[3.3.0.03,7]Octane (bisnoradamantane); solvolysis of its mono and dicarbinols

✍ Scribed by B.Richard Vogt; Stuart R. Suter; John R.E. Hoover

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 220 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)99013-6

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✦ Synopsis

We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV), derived from IV by the deletion of two oppositely situated methylene bridges:

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