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The synthesis of tricyclo[4.3.1.03'8]decane (isoadamantane) and solvolysis of its C3-carbinol

✍ Scribed by B. Richard Vogt


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
150 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis


THE SYNTHESIS 0F ~~rc~~~o[4.3.1.03'~]D~xx~~ (ISOADAMANTANE) AND SOLVOLYSIS OF ITS CJ-CARBINOL


πŸ“œ SIMILAR VOLUMES


A synthesis of tricyclo[3.3.0.03,7]Octan
✍ B.Richard Vogt; Stuart R. Suter; John R.E. Hoover πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 220 KB

We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV)

A highly flexible route to tricyclo[4.3.
✍ P. John Biju; G.S.R. Subba Rao πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 174 KB

An efficient strategy for the construction of and tricyclo[4.3.0.O4'lΒ°]decanes is described which involves a novel one-pot tandem acid-catalyzed rearrangement followed by an ene cyclization as key step and is exemplified by the total synthesis of pupukean-2-one 3.

The Tricyclo[9.3.1.03,8]pentadecane Syst
✍ Prof. Dr. Kenneth J. Shea; Dr. Peter D. Davis πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 235 KB

ture and oxygen over a long period of time[4a1. It was also obtained by reaction of 4 with elemental sulfur (60% yield). Reaction of 2 with chlorine affords 2,4,6-tri-tert-butylphenyfphosphonic dichloride almost quantitatively after hydrolysis'za1. The yields of compounds 2, 3[4b1, and 4 (20-60%, 1