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A highly flexible route to tricyclo[4.3.1.03.7]-, and tricyclo[4.3.0.04,10]decanes A short synthesis of pupukean-2-one

✍ Scribed by P. John Biju; G.S.R. Subba Rao

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 174 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)80053-1

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✦ Synopsis

An efficient strategy for the construction of and tricyclo[4.3.0.O4'l°]decanes is described which involves a novel one-pot tandem acid-catalyzed rearrangement followed by an ene cyclization as key step and is exemplified by the total synthesis of pupukean-2-one 3.

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