The trlcyclc( 4,4,0,03'6) decane system, first synthesized by Whftlock and Siefkenl , has a remarkable geometry, being composed of boat forms twisted in the same sense and existing in two enantlomeric forms Ia and Ib. This chiral system may
The synthesis and the absolute configuration of optically active tricyclo[4.4.0.03.8]decane
β Scribed by Keiichi Adachi; Koichiro Naemura; Masao Nakazaki
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 219 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Die kristalline und molekulare Struktur von 4-Aza-5-oxo-tricyclo[4.4.0.03~8]decan (Aza-twistanon) ## Zusammenfassung Die kristalline Struktur von Aza-twistanon wurde durch eine Rontgenstrukturanalyse untersucht. Die Kristalle gehoren zur monoklinen Raumgruppe P2& mit den Zelldimensionen a = 6,662
Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres