We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV)
Solvolysis of derivatives of tricyclo (3.3.0.03,7) octan-2-ol
β Scribed by R.R. Sauers; B.R. Sickles
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 228 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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Our interest in the hydrocarbon tricyclo[3.3.0.0Jt7 Ioctane (l) has been stimulated by its bisnor relationship to adamantane (zero carbon bridges between C-l-C-5 and C-3-C-7 rather than one carbon bridges), its symmetry (Dad) and the fact that it contains the most twisted norbornane skeleton of reco
## Abstract Tricyclo[3.2.1.0^2,7^]octanβ3βol (**1**) and its 4βisomer **7** were obtained by hydroboration of tricyclo[3.2.1.0^2,7^]octβ3βene (**5**). The former alcohol **1** is quantitatively converted to the isomeric alcohol __exo__βbicyclo[3.2.1]octβ2βenβ7βol (**3**) by treatment with aqueous a