Simple Entry into Tricyclo[3.3.0.03,7]octanes
β Scribed by Hoffmann, H. Martin R. ;El-Khawaga, Ahmed M. ;Oehlerking, Hans-Heinrich
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1991
- Tongue
- English
- Weight
- 115 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0009-2940
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π SIMILAR VOLUMES
Received rn US& 14 Elay 1915: received III UK for publlcatlon 10 June 1075) Recently, Roberts described extension of a reaction, first reported by Mitch and Dreiding,' by which exo-2-bromobicyclo[3.2.O]heptan-6-ones, 1, are transformed by base -
We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV)