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4,6-Dimethylentricyclo[3.3.0.03,7]octan-2-on und 2,4,6-Trimethylentricyclo[3.3.0.03,7]octan

✍ Scribed by Prof. Dr. Rolf Gleiter; Christoph Sigwart; Dr. Bernd Kissler

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
296 KB
Volume
101
Category
Article
ISSN
0044-8249

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✍ Skoda, Lutz ;Klingebiel, Uwe ;Meller, Anton πŸ“‚ Article πŸ“… 1980 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 328 KB

The reaction of mono-and dilithio-2,2,4,4,6,6-hexamethylcyclotrisilazane (1, 2) with aminofluorosilanes R -SiF,-NR'SiMe, (R = F, Me; R' = CMe,, SiMe,) leads to LiF elimination and format'ion of the cyclotrisilazanes 3 -5. The cyclodisilazane 6 is obtained by ring contraction in the reaction of compo