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Dehalogenation of 1,3-Diiodotricyclo[3.3.0.03,7]octane: Generation of 1,3-Dehydrotricyclo[3.3.0.03,7]octane, a 2,5-Methano-Bridged [2.2.1]Propellane

✍ Scribed by Carles Ayats; Pelayo Camps; José A. Fernández; Santiago Vázquez


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
243 KB
Volume
13
Category
Article
ISSN
0947-6539

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✍ Skoda, Lutz ;Klingebiel, Uwe ;Meller, Anton 📂 Article 📅 1980 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 328 KB

The reaction of mono-and dilithio-2,2,4,4,6,6-hexamethylcyclotrisilazane (1, 2) with aminofluorosilanes R -SiF,-NR'SiMe, (R = F, Me; R' = CMe,, SiMe,) leads to LiF elimination and format'ion of the cyclotrisilazanes 3 -5. The cyclodisilazane 6 is obtained by ring contraction in the reaction of compo