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The photochemical isomerization of [Co(NH3)5NO2]X2 in the crystalline state

✍ Scribed by EmilyJ. Rose; DonaldS. McClure

Publisher
Elsevier Science
Year
1981
Weight
84 KB
Volume
17
Category
Article
ISSN
0047-2670

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## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur

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