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Linkage isomerization of [Co(NH3)5ONO]2+ in poly(vinyl alcohol)

✍ Scribed by Andrew W. Zanella; Anthony F. Fucaloro

Publisher
Elsevier Science
Year
1980
Weight
182 KB
Volume
16
Category
Article
ISSN
0020-1650

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Study of the base-catalyzed nitrito–nitr
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## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur

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