The electronic structure of the [(NH3)5CoO2Co(NH3)5]5+ ion
✍ Scribed by I. Hyla-Kryspin; L. Natkaniec; B. Jeżowska-Trzebiatowska
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 344 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
SCCC MO cdculnlions
of the [WH3)sCo02CoWH3)5 1 5i cation were carried out. On the basis ot' the results obtained, the mapnetic properties and bond characters of the compound are discussed. Fin;llly, the electronic structure ol the 0; group as a ligand is analyzed.
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## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur