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Kinetics of nitro-nitrito linkage isomerization [Co(NH3)5NO2]X2 ⇌' [Co(NH3)5ONO]X2 (X=Cl−, Br−, NO3−) in the solid state. Computer simulation and experimental results

✍ Scribed by Elena V. Boldyreva; Anatoly A. Sidelnikov; Nikolai Z. Lyakhov; Kev M. Salikhov

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
188 KB
Volume
92
Category
Article
ISSN
0040-6031

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Study of the base-catalyzed nitrito–nitr
Study of the base-catalyzed nitrito–nitro isomerization reaction ([(NH3)5Co-ONO]2+ → [(NH3)5Co-NO2]2+) in mixed solvents
✍ R. Jiménez; M. Villar; M. Cueto; E. Grueso; J. Illanes; J. I. Cobrian; F. Cantón 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 88 KB

## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur