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The New Silver(I)thioantimonate(III) [C4N2H14] [Ag3Sb3S7] and a New Structural Variant of the Silver(I)thioantimonate(III) [C2N2H9]2 [Ag5Sb3S8] Both Synthesized under Solvothermal Conditions.

✍ Scribed by V. Spetzler; C. Naether; W. Bensch


Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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ChemInform Abstract: New Thioantimonates
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## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.

Solvothermal Synthesis, Crystal Structur
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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 β€’ 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =