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ChemInform Abstract: New Thioantimonates(III) with Different Sb:S Ratios: Solvothermal Syntheses and Crystal Structures of [(C3H10NO)(C3H10N)] [Sb8S13], [(C2H8NO)(C2H8N) (CH5N)][Sb8S13], [(C6H16N2) (C6H14N2)][Sb6S10], and [C8H22N2][Sb4S7].

✍ Scribed by Beatrix Seidlhofer; Volker Spetzler; Enrique Quiroga-Gonzalez; Christian Naether; Wolfgang Bensch


Publisher
John Wiley and Sons
Year
2011
Weight
31 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.


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✍ Michael Schur; Wolfgang Bensch πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 322 KB πŸ‘ 1 views

Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi