## Abstract For Abstract see ChemInform Abstract in Full Text.
Template-Assisted Solvothermal Synthesis of Five Copper(I)-Thioantimonate(III) Composites: Crystal Structures and Optical and Thermal Properties of (C6N2H18) 0.5Cu2SbS3, (C4N3H15) 0.5Cu2SbS3, (C8N4H22) 0.5Cu2SbS3, (C4N3H14) Cu3Sb2S5, and (C6N4H20) 0.5Cu3Sb2S5.
β Scribed by V. Spetzler; C. Naether; W. Bensch
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 25 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi
## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.