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Synthesis and crystal structure of chain [Cu2I2(PPh3)2(C4H5N3)]∞

✍ Scribed by Qiong-Hua Jin; Xiao-Ming Lu; Hui-Ju Zhu; Xian-Ping Ji

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
224 KB
Volume
18
Category
Article
ISSN
0256-7660

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## Abstract The donor‐acceptor complex [(H~3~B){C(PPh~3~)~2~}] (2) has been synthesized by treating B~2~H~6~ with C(PPh~3~)~2~ and its geometry determined by X‐ray structure analysis. Treatment of 2 with DME yields the complex [{(μ‐H)H~4~B~2~}{C(PPh~3~)~2~}][B~2~H~7~] (4), which has also been isola