Novel Copper(I)-Thioantimonates(III): Solvothermal Synthesis, Crystal Structures, Thermal Stability and Magnetic Properties of (C2N2H10) 0.5Cu2SbS3, (C3N2H12) 0.5Cu2SbS3, and (C4N2H14) 0.5Cu2SbS3.
β Scribed by Volker Spetzler; Herme Rijnberk; Christian Naether; Wolfgang Bensch
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 78 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.
The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 β’ 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =