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The isomerization of [Co(NH3)5NO2]Cl2 in potassium chloride discs

✍ Scribed by Beattie, I. R.; Satchell, D. P. N.

Book ID
120323266
Publisher
Royal Society of Chemistry
Year
1956
Weight
312 KB
Volume
52
Category
Article
ISSN
0014-7672

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Study of the base-catalyzed nitrito–nitr
Study of the base-catalyzed nitrito–nitro isomerization reaction ([(NH3)5Co-ONO]2+ → [(NH3)5Co-NO2]2+) in mixed solvents
✍ R. Jiménez; M. Villar; M. Cueto; E. Grueso; J. Illanes; J. I. Cobrian; F. Cantón 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 88 KB

## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur