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Low temperature transients in the solid state photochemical linkage isomerization of [Co(NH3)5NO2]Cl2

✍ Scribed by Dale A. Johnson; Karen A. Pashman

Book ID: 107768849
Publisher: Elsevier Science
Year: 1975
Weight: 177 KB
Volume: 11
Category: Article
ISSN: 0020-1650
DOI: 10.1016/0020-1650(75)80141-3

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## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur