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The Formation of a 1,3,6-Cycloöctatriene by 1,4-Radical Addition to Cycloöctatetraene and its Intramolecular Isomerization to a Bicyclo [4.2.0]octa-2,4-diene

✍ Scribed by Kice, John L.; Cantrell, Thomas S.


Book ID
126783801
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
735 KB
Volume
85
Category
Article
ISSN
0002-7863

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The radical cation of 1,4-dihydropentale
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In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj