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Photoinduced electrocyclic 1,5-closure of the cyclooctatetraene radical cation to a bridged 1,4-bishomobenzene (bicyclo[3.3.0]octa-2,6-diene-4,8-diyl) radical cation

✍ Scribed by Dai, Sheng; Wang, Jih Tzong; Williams, Ffrancon


Book ID
127367655
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
453 KB
Volume
112
Category
Article
ISSN
0002-7863

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The radical cation of 1,4-dihydropentale
✍ Thomas Bally; Leo Truttmann; Sheng Dai; Jih Tzong Wang; Ffrancon Williams 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 761 KB

In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj