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Isomerization of the cubane radical cation to the bridged 1,4-bishomobenzene (bicyclo[3.3.0]octa-2,6-diene-4,8-diyl) radical cation

✍ Scribed by Qin, X. Z.; Trifunac, A. D.; Eaton, P. E.; Xiong, Y.


Book ID
127311589
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
399 KB
Volume
112
Category
Article
ISSN
0002-7863

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The radical cation of 1,4-dihydropentale
✍ Thomas Bally; Leo Truttmann; Sheng Dai; Jih Tzong Wang; Ffrancon Williams 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 761 KB

In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj