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Cyclic Polyolefins. XXIII. Valence Tautomerism of 1,3,5-Cycloöctatriene and Bicyclo [4.2.0]octa-2,4-diene 1

✍ Scribed by Cope, Arthur C.; Haven, Alfred C.; Ramp, Floyd L.; Trumbull, Elmer R.


Book ID
127299344
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
694 KB
Volume
74
Category
Article
ISSN
0002-7863

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Kinetic and equilibrium study of gas-pha
✍ John M. Greathead; S. Walter Orchard 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 589 KB

## Abstract The gas‐phase equilibrium and rate constants for the isomerizations of 1,3,6‐cyclooctatriene (136COT) to 1,3,5‐cyclooctatriene (135COT) [reaction (1)] and bicyclo[4.2.0]octa‐2,4‐diene (BCO) to 135COT [reaction (‐2)] have been measured between 390 and 490 K and between 330 and 475 K, res