Vibrational Spectra of 1,3,5-Cycloöctatriene, Bicyclo [4.2.0]octa-2,4-diene and their Dichlorides
✍ Scribed by Lippincott, E. R.; Lord, R. C.
- Book ID
- 127343970
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 305 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The gas‐phase equilibrium and rate constants for the isomerizations of 1,3,6‐cyclooctatriene (136COT) to 1,3,5‐cyclooctatriene (135COT) [reaction (1)] and bicyclo[4.2.0]octa‐2,4‐diene (BCO) to 135COT [reaction (‐2)] have been measured between 390 and 490 K and between 330 and 475 K, res
According to the observations and data reported by Willstutter and Wuser [4], rather pure COT may have been obtained in their first attempt to synthesize this compound. Note also that independent from Cope and Hochstein [l], Ziegler and Wilms [3b] carefully separated the products obtained by reducti