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Electronic and Molecular Structure of the C8H Valence Isomers 1,3,5-Cyclooctatriene+· and Bicyclo[4.2.0]octa-2,4-diene+· from their Electronic absorption Spectra in Freon

✍ Scribed by Thomas Bally; Kuno Roth; Rolf Straub

Publisher: John Wiley and Sons
Year: 1989
Tongue: German
Weight: 590 KB
Volume: 72
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19890720110

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✦ Synopsis

According to the observations and data reported by Willstutter and Wuser [4], rather pure COT may have been obtained in their first attempt to synthesize this compound. Note also that independent from Cope and Hochstein [l], Ziegler and Wilms [3b] carefully separated the products obtained by reduction of cyclooctatetraene with Na and found COT and bicyclo[4.2.0]octadiene to which they erroneously assigned the 3,6-diene structure.

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