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The flash thermolysis of 3-isopropylidenetricyclo [ 3.2.1.02,4]oct-6-ene: A new rearrangement to the cyclooctatetraene system

โœ Scribed by R. Bloch; F. Leyendecker; N. Toshima

Book ID
104246827
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
232 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

to mesitylene was reported in 1 it. (2~). 18. Calibrated from relative yields.

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In the preceding cosxnunication,l we noted that the ozonoly~is of 6,7-dimethoxy-exo--tricyclcf3.2.1.02'4]oct-6-ene (1) in methanol gave 7,7-dimethoxy-z-tricycq3.2.1.02'~act-6-one (2), in addition to the expected osonolysis product 3. We now wieh to report -our mechanistic studies related to this eno