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The thermal rearrangements of the 6,7-disubstituted 3-benzenesulfonyl-3-azatricyclo[3.2.1.02,4exo]oct-6-enes

✍ Scribed by Katsumi Umano; Hisaji Taniguchi; Hiroo Inoue; Eiji Imoto

Book ID
108384712
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
197 KB
Volume
20
Category
Article
ISSN
0040-4039

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## Photochemical Rearrangement of exo-3,6,7-Trioxatricyclo[3.2.2.0 2,4 ]nonane. -The photolysis of trioxatricyclononane (I) in the presence of dicyanoanthracene as sensitizer in methanol gives a mixture of nine products [e.g. (III)-(IX)]. The mechanism is discussed and compared with the results o