ChemInform Abstract: Photochemical Rearrangement of exo-3,6,7-Trioxatricyclo[3.2.2.02,4]nonane.

✍ Scribed by N. I. KURBANOGLU; Y. KARA; H. SECEN; N. AKBULUT

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 37 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199809039

✦ Synopsis

Photochemical

Rearrangement of exo-3,6,7-Trioxatricyclo[3.2.2.0 2,4 ]nonane.

-The photolysis of trioxatricyclononane (I) in the presence of dicyanoanthracene as sensitizer in methanol gives a mixture of nine products [e.g. (III)-(IX)]. The mechanism is discussed and compared with the results of a earlier published thermolysis of (I). -(KURBANOGLU, N. I.;