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ChemInform Abstract: Photochemical Rearrangement of 3,3,6-Trimethyl-1,5-heptadien-4-one.

✍ Scribed by O. A. Luzina; S. M. Adekenov; E. M. Suleimenov; G. A. Atazhanova; N. F. Salakhutdinov; V. A. Barkhash

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200201071

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## Photochemical Rearrangement of exo-3,6,7-Trioxatricyclo[3.2.2.0 2,4 ]nonane. -The photolysis of trioxatricyclononane (I) in the presence of dicyanoanthracene as sensitizer in methanol gives a mixture of nine products [e.g. (III)-(IX)]. The mechanism is discussed and compared with the results o