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The anomalous ozonolysis of 6,7-dimethoxy-exo-tricyclo[3.2.1.02,4]oct-6-ene

โœ Scribed by Paul G. Gassman; Xavier Creary

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
171 KB
Volume
13
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

In the preceding cosxnunication,l we noted that the ozonoly~is of 6,7-dimethoxy-exo--tricyclcf3.2.1.02'4]oct-6-ene (1) in methanol gave 7,7-dimethoxy-z-tricycq3.2.1.02'~act-6-one (2), in addition to the expected osonolysis product 3. We now wieh to report -our mechanistic studies related to this enomalous oxidation of 1 to 2.

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