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Regiospecific addition of TCNE to 2-exo-methyl-endo-tricyclo [3.2.1.02,4] oct-6-ene

✍ Scribed by J.M. Coxon; M. de Bruijn; C.K. Lau

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 173 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)71858-2

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In the preceding cosxnunication,l we noted that the ozonoly~is of 6,7-dimethoxy-exo--tricyclcf3.2.1.02'4]oct-6-ene (1) in methanol gave 7,7-dimethoxy-z-tricycq3.2.1.02'~act-6-one (2), in addition to the expected osonolysis product 3. We now wieh to report -our mechanistic studies related to this eno