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Synthesis and Homo-Diels-Alder Cleavage of the Epoxy-azoalkaneexo-3-Oxa-6,7-diazatricyclo[3.2.1.02,4]oct-6-ene

✍ Scribed by Adam, Waldemar ;Berkessel, Albrecht


Publisher
Wiley (John Wiley & Sons)
Year
1985
Tongue
English
Weight
367 KB
Volume
118
Category
Article
ISSN
0009-2940

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## Abstract The 1,3‐dipolar addition reaction of acrylonitrile to the betaine 1‐phenyl or methyl‐3‐oxidopyridinium is not so highly regioselective as generally assumed. New regioisomers are isolated. Their structures are proven by mass spectroscopy and proton‐and carbon‐NMR spectroscopy. Some 3,4di