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New evidence in the iridium(I)-catalyzed reaction of endo-tricyclo[3.2.1.02,4]oct-6-ene

โœ Scribed by Campbell, H.; Jennings, P. W.


Book ID
127168612
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
273 KB
Volume
2
Category
Article
ISSN
0276-7333

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We report a striking example of unprecedented regiospecificity in the addition of acetic acid to endo-tricyclo[3.2.1.0z"]oct-6-ene (1). The addition proceeds with surprising ease in acetic acid at 80' (3 days) or at room temperature in the presence of catalytic amounts of toluenesulphonic acid to yi