Rhodium(I)-catalyzed valence isomerization of exo-tricyclo[3.2.1.02,4]oct-6-ene
โ Scribed by Vogler, H. C.; Hogeveen, Hepke; Gaasbeek, M. M. P.
- Book ID
- 127003194
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 250 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
In the preceding cosxnunication,l we noted that the ozonoly~is of 6,7-dimethoxy-exo--tricyclcf3.2.1.02'4]oct-6-ene (1) in methanol gave 7,7-dimethoxy-z-tricycq3.2.1.02'~act-6-one (2), in addition to the expected osonolysis product 3. We now wieh to report -our mechanistic studies related to this eno
In 1966 it was first reported that rhodium catalyzes a cycloaddition reaction (norbornadiene + 5% Rh/C) (1). Subsequently similar reactions were found to occur not only with some other hydrocarbons and rhodium on carbon (2), but also with coordination complexes of rhodium