The First Triisopropylstibane Ruthenium(II) and Ruthenium(0) Complexes Including the X-ray Crystal Structure of [Ru(η3-C3H5)2(SbiPr3)2]
✍ Scribed by Werner, Helmut ;Gr ünwald, Claus ;Laubender, Matthias ;Gevert, Olaf
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1996
- Tongue
- English
- Weight
- 481 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2940
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## Abstract The 16‐e^−^ (η^3^‐allyl)‐ruthenium(II) complex [Ru(η^3^‐2‐C~3~H~4~Me)(CO)(dppf)][SbF~6~] is an efficient catalyst for the regioselective isomerization of terminal propargylic alcohols HCCCR^1^R^2^(OH) into α,β‐unsaturated aldehydes R^1^R^2^CCHCHO or ketones R^3^R^4^CC(R^1^)COMe (if R
Complexes of Ni II , Cu II , Zn II , and Co III containing the 1,2,6,7tetracyano-3,5-dihydro-3,5-diiminopyrrolizinide (L) and the 2,4-tert-butylacetylacetonide (DPM) ligands have been synthesized and characterized. The absorption optical spectra of these species and of the corresponding ML 2 complex