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X-Ray Structure Determination of Tris (1, 4, 5, 8-Tetraazaphenanthrene) Ruthenium (ii) Dichloride Dihydrate, (C10H6N4) 3Ru (II) Cl2.2H2O

✍ Scribed by C. Piccinni-Leopardi; M. van Meerssche; J. P. Declercq; G. Germain


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
89 KB
Volume
96
Category
Article
ISSN
0037-9646

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✍ Marjaana Mikola; Karel D. Klika; Jorma Arpalahti πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 261 KB πŸ‘ 2 views

In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking