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Synthesis of Hydride Tantalabenzocyclopentene and µ-Alkylidene Complexes by Direct Alkylation Reactions of [TaCp*Cp′Cl2] − NMR Spectroscopic Study and X-ray Crystal Structure of [TaCp*Cp′(H)(η2-CH2-CMe2-o-C6H4)], (Cp* = η5-C5Me5; Cp′ = η5-C5H4SiMe3)

✍ Scribed by Aurora Castro; Mikhail V. Galakhov; Manuel Gómez; Pilar Gómez-Sal; Avelino Martín


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
170 KB
Volume
2002
Category
Article
ISSN
1434-1948

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The Influence of the Ligands Cp*(η5-C5Me
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,