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[Cp2V(μ-η2:η4-butadiyne)MCp2′] (M=Ti, Zr; Cp′=C5H5, C5H4SiMe3): Heterodimetallic Complexes from a Bis(alkynyl)metallocene and Vanadocene—Unexpected Structure of [Cp2V(μ-η2:η4-butadiyne)Zr(C5H4SiMe3)2] Containing Two Planar-Tetracoordinate Carbon Atoms

✍ Scribed by Christine Danjoy; Jianshe Zhao; Bruno Donnadieu; Jean-Pierre Legros; Lydie Valade; Robert Choukroun; Antoine Zwick; Patrick Cassoux

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
132 KB
Volume
4
Category
Article
ISSN
0947-6539

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✍ Vinicius Caliman; Peter B. Hitchcock; J. F. Nixon 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 376 KB 👁 2 views

The first examples of g 1 -complexes of 1,2,4-triphospholes are reported in which the ring acts as a 2e and a 4e donor.