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Synthesis and X-ray Structure of [{(Cp′2Nb)2WTe4}⋅W(CO)4]·1.5C7H8, the First Organometallic Derivative of the WTe42− Anion, and of [Cp′4Nb2Te2] (Cp′ = η5-tBuC5H4)

✍ Scribed by Henri Brunner; Joachim Wachter; Robert Wanninger; Manfred Zabel


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
308 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4