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The dynamics of barrier crossings in solution: The effect of a solvent polarity-dependent barrier

✍ Scribed by Janice Hicks; Mark Vandersall; Zoran Babarogic; Kenneth B. Eisenthal

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 650 KB
Volume: 116
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80117-2

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✦ Synopsis

Expenmcnts

on the role of the solvent m the dynamtcs of photolsomenzalton rnvolvrng lnrgc dtpolc moment chnnges are dtscussed Vanatton of the phototsomenzatton dynnmtcs of dtmethylamtnobenzonttnle tn a sencs of solvents IS attnbutcd chletly !o polanty-Induced barrier height changes rather than VISCOSII~ changes lmphcattons of these rmdmgs regardmg the use of bamer crowng lhcortes arc dtscussed ' Intematlonai Atonuc Energy Fellow, Vienna. Austna ' Permanent address lnsfitute of Phystcs.

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