## Expenmcnts on the role of the solvent m the dynamtcs of photolsomenzalton rnvolvrng lnrgc dtpolc moment chnnges are dtscussed Vanatton of the phototsomenzatton dynnmtcs of dtmethylamtnobenzonttnle tn a sencs of solvents IS attnbutcd chletly !o polanty-Induced barrier height changes rather than
Polarity-dependent barriers and the photoisomerization dynamics of molecules in solution
β Scribed by J.M. Hicks; M.T. Vandersall; E.V. Sitzmann; K.B. Eisenthal
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 760 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The influence of various solvents (water, methanol, diethyl ether, n-hexane, cyclohexane, as well as of mixtures) and of the excitation energy (h exe) on the fiuorescence quantum yield (QF) of phenol has been investigated in 02free solutions. At excitation energies above 5.1 eV (&c < 240 nm) a stron
## A calculation of the absorption profile of a polar diatomic molecule dissolved in a non -polar solvent is presented. The agreement with experimental data suggests to consider that the dynamical state of
The dynamics of tRNAPhe from brewer's yeast in solution was studied over a broad concentration and temperature range by polarized and depolarized dynamic light scattering. It is shown that measurements of the depolarized Rayleigh spectrum with a high-resolution confocal Fabry-Perot interferometer pr