We report the first observation of a reaction which, in a single solvent, starts as a barrier crossing process at low pressure and turns into a relaxation on a banierless potential at high pressure. The pressure and temperature dependences of trans-stilbene photoisomerization in n-alkanols were inve
Pressure dependence of solvent-induced barrier shifts in the photoisomerization of trans-stilbene
✍ Scribed by J. Schroeder; J. Troe; P. Vöhringer
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 583 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0009-2614
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The rate of y-ray-induced trans -cis isomerization of stilbene in dilute toluene solutions from -95o to A1OOo shows a maximum at about -25O. The results are interpreted in terms of interplay of opposing reactions. and of the role of triplet toluene.
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