A spiro attack on a peroxo group is calculated to be the preferred reaction pathway for olefin epoxidation with the catalytic system CH ReO /H O (see picture). This finding is supported by density functional calculations on more than ten transition states for the most probable mechanisms. Hydration
Solvent Effects on the Activation Barriers of Olefin Epoxidation − A Density Functional Study
✍ Scribed by Philip Gisdakis; Notker Rösch
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 247 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-193X
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